Catalyst-free, aza-Michael polymerization of hydrazides: polymerizability, kinetics, and mechanistic origin of an ?-effect

Polym. Chem., 2019, 10,5790-5804DOI: 10.1039/C9PY01199D, PaperDillon Love, Kangmin Kim, Dylan W. Domaille, Olivia Williams, Jeffrey Stansbury, Charles Musgrave, Christopher Bowman?-Effect observed in unsubstituted hydrazide nucleophiles imbues highly efficient bis-addition reactivity in the aza-Michael reaction of hydrazides, in contrast to primary alkyl amines.The content of this RSS Feed (c) The Royal Society of Chemistry

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