What's the right thing to say to someone with cancer?

This cancer survivor is changing the "sugarcoated" greeting card business

Anjali: The professional dance company with a difference

Anjali's dancers, who have learning disabilities, are working with world-renowned choreographers.

Germany's other vote: Tegel airport row divides Berliners

Berliners hold a vote on the future of Tegel airport - and it has become a hot political issue.

'I want to get rid of my Polish accent'

Kasha lives in the UK but has found some people are hostile because of her Polish accent.

A modern muse: The enduring appeal of Audrey Hepburn

Hundreds of the Hollywood actor's personal items are on display at Christie's ahead of an auction.

The island where people eat puffins

In a remote corner of Iceland, the taste of the seabird is a reminder of home.

Soul singer Charles Bradley dies aged 68

The singer, who released his first album in his 60s, cancelled tour dates just two weeks ago.

What's Going to Happen Before 2050?

The future will bring both exciting events and new dangers.

How Cuba and Puerto Rico responded to their hurricanes

Cuba and Puerto Rico responded differently to devastating hurricanes, the BBC's Will Grant reports.

'Hey, Walmart, please use my API instead of your EDI'

Survey of 900 IT executives finds rising adoption of cloud-based integration; search is on for holistic approaches.

'Hey, Walmart, please use my API instead of your EDI'

Survey of 900 IT executives finds rising adoption of cloud-based integration; search is on for holistic approaches.

PodPocket provides protection and a way to carry your AirPods

I enjoy using my Apple AirPods headset during my commute, but don't like that the carrying case gets lost in my gear bag. For $20 PodPocket solves that problem.

Video Roundup: New in smartphones

Late summer and early autumn is always a busy time of year for smartphones. This year is no exception.

Video Roundup: New in smartphones

Late summer and early autumn is always a busy time of year for smartphones. This year is no exception.

9 Solar Lanterns for Giving Off Light When You're Nowhere Near an Outlet

Why spend money on batteries or electricity when you can steal light from the sun?

North Korea: Tremor detected near weapon test site

It remains unclear if the magnitude 3.4 tremor was caused by an explosion or a natural event.

18 Reasons Blue Ridge Parkway is the Most Spectacular Place to Experience Autumn

There is no better place in the country to take in the fall foliage.

Iran tests missile despite Trump pressure

The launch of the Khoramshahr missile, with a range of 2,000km, was shown on state TV.

Trump rails against Republican Obamacare rebels

Republicans who refuse to back repeal legislation lack "guts", the US president says.

Uber petition over London licence loss reaches 500,000

An online petition was launched after it was announced Uber would lose its London licence.

Computational Characterization of the Mechanism for the Light-Driven Catalytic Trichloromethylation Of Acylpyridines

Org. Biomol. Chem., 2017, Accepted ManuscriptDOI: 10.1039/C7OB01826F, PaperVictor M Fernandez-Alvarez, Feliu MaserasThe computational characterization of the mechanism for complex reactions involving the photoactivation of transition metal compounds remains a challenge for theoretical chemistry. In this work we show how the application...The content of this RSS Feed (c) The Royal Society of Chemistry

On the Regiochemical Differences between Pd-Catalyzed Heterocyclization-Allylation and -Arylation Reactions of Alkynylbenzamides: Preparation of 4-Allyl-isochromen-1-imines and Computational Study

Org. Biomol. Chem., 2017, Accepted ManuscriptDOI: 10.1039/C7OB02117H, PaperRosana Alvarez, Unai Vilar, Youssef Madich, Jose M. AurrecoecheaThe Pd(0)-catalyzed cyclization-allylation reactions of 2-alkynylbenzamides proceed with high regioselectivity to afford the 6-endo-cyclization-derived products 4-allyl-isochromen-1-imines.

A Convenient Synthesis of 1-Aryl-1H-1,2,3-triazoles from Aliphatic Substrates

Org. Biomol. Chem., 2017, Accepted ManuscriptDOI: 10.1039/C7OB02035J, PaperQiang Wang, Xiaonan Shi, Xinying Zhang, Xuesen FanA convenient synthesis of 1-aryl-1H-1,2,3-triazoles through the one pot cascade reactions of alkynes with aliphatic azides and allenic ketones is presented. Mechanically, the formation of the title compounds involves a...The content of this RSS Feed (c) The Royal Society of Chemistry

ESIPT-Induced Fluorescent o-Hydroxycinnamate: Self-Monitoring Phototrigger for Prompt Image-Guided Uncaging of Alcohols

Org. Biomol. Chem., 2017, Accepted ManuscriptDOI: 10.1039/C7OB02280H, PaperAmrita Paul, Rakesh Mengji, Olive Abraham Chandy, Surajit Nandi, Manoranjan Bera, Avijit Jana, Anakuthil Anoop, Pradeep N.D. SinghThe o-hydroxycinnamate derivatives are well known phototriggers for fast and direct release of alcohols and amines without proceeding through the cleavage of carbonate or carbamate linkages.

Mechanism of Supplemental Activator and Reducing Agent Atom Transfer Radical Polymerization Mediated by Inorganic Sulfites: Experimental Measurements and Kinetic Simulations

Polym. Chem., 2017, Accepted ManuscriptDOI: 10.1039/C7PY01319A, PaperPawel Krys, Marco Fantin, Patricia Mendonca, Carlos M. R. Abreu, Tamaz Guliashvili, Jaquelino Rosa, Lino Santos, Armenio Coimbra Serra, Krzysztof Matyjaszewski, Jorge CoelhoThe mechanism of atom transfer radical polymerization (ATRP) mediated by sodium dithionite (Na2S2O4), with CuIIBr2/Me6TREN as catalyst (Me6TREN: tris[2-(dimethylamino)ethyl]amine)) in ethanol/water mixtures, was investigated experimentally and by kinetic simulations.

Hydrogels through Emulsion Templating: Sequential Polymerization and Double Networks

Polym. Chem., 2017, Accepted ManuscriptDOI: 10.1039/C7PY01305A, PaperSebastijan Kovacic, Michael S. SilversteinDouble-network (DN) hydrogels combine two very different polymer networks. Here, porous hydrogels with DN structures were successfully synthesized in two sequential free-radical polymerization steps. The first network was templated within...The content of this RSS Feed (c) The Royal Society of Chemistry

Asli Cakir Alptekin: Life ban for winner of 'dirtiest race in history'

Former Olympic champion Asli Cakir Alptekin is given a life ban by the Turkish Athletics Federation after a third doping offence.

US student trapped in Indiana cave for three days

Lukas Cavar, 19, says he had to lick the walls of the cave for moisture during his three day ordeal.

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